Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis
This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstitute...
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| Materialtyp: | Elektronisk E-bok |
| Språk: | engelska |
| Publicerad: |
Singapore :
Springer Nature Singapore : Imprint: Springer,
2024.
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| Upplaga: | 1st ed. 2024. |
| Serie: | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Länkar: | https://doi.org/10.1007/978-981-99-8994-2 |
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| 100 | 1 | |a Go, Su Yong. |e author. |4 aut |4 http://id.loc.gov/vocabulary/relators/aut | |
| 245 | 1 | 0 | |a Photochemical and Electrochemical Activation Strategies of C(sp3)-Based Building Blocks for Organic Synthesis |h [electronic resource] / |c by Su Yong Go. |
| 250 | |a 1st ed. 2024. | ||
| 264 | 1 | |a Singapore : |b Springer Nature Singapore : |b Imprint: Springer, |c 2024. | |
| 300 | |a XXVII, 169 p. 257 illus., 166 illus. in color. |b online resource. | ||
| 336 | |a text |b txt |2 rdacontent | ||
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| 341 | 0 | |b Single logical reading order |2 onix | |
| 341 | 0 | |b Short alternative textual descriptions |2 onix | |
| 341 | 0 | |b Use of color is not sole means of conveying information |2 onix | |
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| 490 | 1 | |a Springer Theses, Recognizing Outstanding Ph.D. Research, |x 2190-5061 | |
| 505 | 0 | |a Part I. C(sp2)-C(sp3) Bond Formation Reactions Enabled by Photoredox/Nickel Dual Catalysis -- Chapter 1. The Key Concepts and Strategy in Photoredox/Nickel Dual Catalysis and Application to C-C Bond Formation Reactions -- Chapter 2. Highl Regioselective and E/Z Selective Hydroalkylation of Alkyne via Photoredox Mediated Ni/Ir Dual Catalysis -- Part II. Development of C(sp3)-Heteroatom Bond-Forming Reactions via Electrochemical Activation of C(sp3)-B Bonds and Follow-up Projects -- Chapter 3. Recent Achievements of C(sp3)-Heteroatom Bond Formation in Electroorganic Synthesis and History of C(sp3)-B Bond Activation -- Chapter 4. Introduction of Heteroatoms to Alkyl Carbocations Generated from Alkylboron Reagents via Electrochemical Activation -- Chapter 5. Functionalization of Alkylboron Compounds Under Other Reaction Conditions. | |
| 520 | |a This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization. The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, although the backbone structure of organic compounds comprises carbon fragments. | ||
| 532 | 8 | |a Accessibility summary: This PDF does not fully comply with PDF/UA standards, but does feature limited screen reader support, described non-text content (images, graphs), bookmarks for easy navigation and searchable, selectable text. Users of assistive technologies may experience difficulty navigating or interpreting content in this document. We recognize the importance of accessibility, and we welcome queries about accessibility for any of our products. If you have a question or an access need, please get in touch with us at accessibilitysupport@springernature.com. | |
| 532 | 8 | |a No reading system accessibility options actively disabled | |
| 532 | 8 | |a Publisher contact for further accessibility information: accessibilitysupport@springernature.com | |
| 650 | 0 | |a Electrochemistry. | |
| 650 | 0 | |a Photochemistry. | |
| 650 | 0 | |a Catalysts. | |
| 650 | 0 | |a Catalysis. | |
| 650 | 0 | |a Materials. | |
| 650 | 1 | 4 | |a Electrochemistry. |
| 650 | 2 | 4 | |a Photochemistry. |
| 650 | 2 | 4 | |a Catalyst Synthesis. |
| 650 | 2 | 4 | |a Catalytic Materials. |
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| 776 | 0 | 8 | |i Printed edition: |z 9789819989935 |
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| 830 | 0 | |a Springer Theses, Recognizing Outstanding Ph.D. Research, |x 2190-5061 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/978-981-99-8994-2 |
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| 950 | |a Chemistry and Materials Science (SpringerNature-11644) | ||
| 950 | |a Chemistry and Material Science (R0) (SpringerNature-43709) | ||