Synthesis of Aziridines and Oxaziridines from Imines /
The smallest possible saturated azaheterocycle, aziridine, is well-known to organic chemists for its tremendous potential in pharmaceutical chemistry and organic synthesis. The general biological importance of aziridines is proven by the fact that they found several uses as subunits in pharmacologic...
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| フォーマット: | 電子媒体 eBook |
| 言語: | 英語 |
| 出版事項: |
Amsterdam :
Elsevier,
2024.
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| オンライン･アクセス: | ScienceDirect |
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| 005 | 20260915095220.0 | ||
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| 008 | 240120s2024 ne o 000 0 eng d | ||
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| 050 | 4 | |a TP248.A9 | |
| 082 | 0 | 4 | |a 661.894 |1 https://id.oclc.org/worldcat/ddc/E3wtxYVYj9rj8PKy34qJtJyjqV |
| 100 | 1 | |a Kaur, Navjeet. | |
| 245 | 1 | 0 | |a Synthesis of Aziridines and Oxaziridines from Imines / |c Navjeet Kaur. |
| 260 | |a Amsterdam : |b Elsevier, |c 2024. | ||
| 300 | |a 1 online resource (354 p.) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |2 rdamedia | ||
| 338 | |a online resource |2 rdacarrier | ||
| 500 | |a Description based upon print version of record. | ||
| 505 | 0 | |a Front Cover -- Synthesis of Aziridines and Oxaziridines from Imines -- Copyright Page -- Contents -- About the author -- Preface -- Abbreviations -- 1 Aziridine synthesis from imines-I -- 1.1 Introduction -- 1.2 Synthesis of aziridines from imines -- 1.3 Synthesis of aziridines from two imines -- References -- 2 Aziridine synthesis from imines-II -- 2.1 Introduction -- 2.2 Synthesis of aziridines from imines and carbonyl compounds -- 2.3 Synthesis of aziridines from imines and halomethane compounds -- 2.4 Synthesis of aziridines from imines and sulfur-containing compounds -- References | |
| 505 | 8 | |a 3 Aziridine synthesis by condensation of phenylimines with ethyl diazoacetate -- 3.1 Introduction -- 3.2 Synthesis of aziridines from phenylimines and ethyl diazoacetate -- 3.3 Synthesis of aziridines from phenylimines and ethyl diazoacetate using boron trifluoride -- 3.4 Synthesis of aziridines from phenylimines and ethyl diazoacetate using imidazolium ionic liquids -- 3.5 Synthesis of aziridines from phenylimines and ethyl diazoacetate using pyridinium salts -- 3.6 Synthesis of aziridines from phenylimines and ethyl diazoacetate using VAPOL or VANOL -- References | |
| 505 | 8 | |a 4 Aziridine synthesis by metal-catalyzed condensation of phenylimines with ethyl diazoacetate -- 4.1 Introduction -- 4.2 Metal-catalyzed synthesis of aziridines from phenylimines and ethyl diazoacetate -- 4.3 Copper-catalyzed synthesis of aziridines from phenylimines and ethyl diazoacetate -- 4.4 Iron-catalyzed synthesis of aziridines from phenylimines and ethyl diazoacetate -- References -- 5 Aziridine synthesis by the addition of biphenyl imines to ethyl diazoacetate -- 5.1 Introduction -- 5.2 Synthesis of aziridines from biphenyl imines and ethyl diazoacetate | |
| 505 | 8 | |a 5.3 Synthesis of aziridines from biphenyl imines and ethyl diazoacetate using vaulted chiral ligands binaphthol (VANOL) and... -- References -- 6 Aziridine synthesis by metal-catalyzed addition of biphenyl imines to ethyl diazoacetate -- 6.1 Introduction -- 6.2 Metal-catalyzed synthesis of aziridines from biphenyl imines and ethyl diazoacetate -- 6.3 Ruthenium-catalyzed synthesis of aziridines from biphenyl imines and ethyl diazoacetate -- References -- 7 Aziridine synthesis by condensation of imines with diazo compounds -- 7.1 Introduction -- 7.2 Synthesis of aziridines from diazoimines | |
| 505 | 8 | |a 7.3 Synthesis of aziridines from imines and diazo compounds -- 7.4 Synthesis of aziridines from imines and diazoacetamides -- 7.5 Synthesis of aziridines from imines and t-butyl diazoacetates -- References -- 8 Aziridine synthesis by condensation of imines with diazomethane -- 8.1 Introduction -- 8.2 Synthesis of aziridines from imines and diazomethane -- 8.3 Synthesis of aziridines from imines and trimethylsilyldiazomethane -- 8.4 Synthesis of aziridines from imines and phenyldiazomethane -- References -- 9 Aziridine synthesis by ring-closure of haloimines -- 9.1 Introduction | |
| 500 | |a 9.2 Synthesis of aziridines from haloimines | ||
| 520 | |a The smallest possible saturated azaheterocycle, aziridine, is well-known to organic chemists for its tremendous potential in pharmaceutical chemistry and organic synthesis. The general biological importance of aziridines is proven by the fact that they found several uses as subunits in pharmacologically active compounds such as antitumor agents, enzyme inhibitors, and antibiotics. Although aziridines are highly reactive, this framework occurs in many synthetic compounds and the natural products of biological interest also contain aziridine skeleton in their structures.The synthetic community is captivated with prospects of selective synthesis and conversions of aziridines. Several important advances in this area have been witnessed in recent years and discovering efficient novel methods for the synthesis of aziridines has been very active field of research. Its powerful synthetic utility has been described by an overpowering amount of documentation on the approaches for the formation of aziridine.Synthesis of Aziridines and Oxaziridines from Imines describes the new and old methods for the synthesis of aziridines from imines and covers an important and rapidly growing branch of heterocyclic chemistry. Readers will have access to different methods and information allowing them to evaluate which method is most suitable for particular cases.- Focuses on the biological importance of different heterocycles- Describes traditional and innovative methods for the synthesis of aziridines from imines- Includes comparison amongst different methods, reagents, reaction conditions in tabulated forms, advantages, disadvantages, and critical analysis of different methodologies with respect to their comparison with green technique. | ||
| 504 | |a Includes bibliographical references and index. | ||
| 650 | 0 | |a Aziridines. | |
| 650 | 6 | |a Aziridines. |0 (CaQQLa)201-0038749 | |
| 650 | 7 | |a Aziridines |2 fast |0 (OCoLC)fst01743606 | |
| 776 | 0 | 8 | |i Print version: |a Kaur, Navjeet |t Synthesis of Aziridines and Oxaziridines from Imines |d San Diego : Elsevier,c2024 |z 9780443220593 |w (OCoLC)1389877628 |
| 856 | 4 | 0 | |3 ScienceDirect |u https://www.sciencedirect.com/science/book/9780443220593 |