Advances in thermoplastic elastomers : challenges and opportunities /
This book delves into the advancements in thermoplastic elastomers (TPEs), focusing on their synthesis, properties, and applications. Edited by experts in the field, it covers a wide range of topics including block copolymer phase separation, thermoplastic vulcanizates, and the chemistry of blending...
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| Altri autori: | , |
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| Natura: | eBook |
| Lingua: | inglese |
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Amsterdam :
Elsevier,
2024.
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| Accesso online: | ScienceDirect |
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| 245 | 0 | 0 | |a Advances in thermoplastic elastomers : |b challenges and opportunities / |c edited by Nikhil K. Singha, Sadhan C. Jana. |
| 260 | |a Amsterdam : |b Elsevier, |c 2024. | ||
| 300 | |a 1 online resource | ||
| 500 | |a Includes indexes. | ||
| 588 | 0 | |a Print version record. | |
| 505 | 0 | |a Front Cover -- Advances in Thermoplastic Elastomers -- Advances in Thermoplastic Elastomers: Challenges and Opportunities -- Copyright -- Dedication -- Contents -- List of contributors -- Preface -- 1 -- Introduction -- 1. Background and historical aspects -- 2. An introduction to TPEs -- 3. Classification of TPE and types of polymers used for the synthesis of TPEs -- 4. Thermoplastic vulcanizates -- 5. Sustainable TPEs -- 6. Processing of TPEs -- 6.1 Additives -- 7. Applications of TPEs -- 8. TPE market -- References -- 2 -- TPEs and TPVs from research to commercialization including patents and published literature -- 1. Thermoplastic elastomers (TPE) -- 2. Thermoplastic vulcanizates (TPV) -- 3. Research versus commercial development [12,13] -- 4. TPE: Polyurethane -- 5. Polyolefin TPE -- 6. TPV PP/EPDM and similar -- 6.1 Development -- 6.2 TPV engineering thermoplastics/rubbers -- 6.3 PP/EPDM process development -- 6.4 PP/EPDM structure-property development -- 7. Conclusion -- References -- 3 -- Block copolymer phase separation basics, thermodynamics, and applications in thermoplastic elastomers -- 1. Introduction -- 2. Block copolymers: fundamentals -- 3. Characterization tools for phase segregation -- 3.1 Differential scanning calorimetry -- 3.2 Dynamic mechanical thermal analysis -- 3.3 Small angle X-ray scattering -- 3.4 Wide-angle X-ray scattering -- 3.5 Transmission electron microscopy -- 4. Ways to control the morphology of the block copolymers: a platform for nanofabrication -- 4.1 Nanofabrication using block copolymers -- 4.2 Orientation of BCP nanostructures -- 4.3 The process of DSA of BCPs -- 4.4 Nanolithography -- 4.5 Nanoreactors for the generation of nanoparticles -- 4.6 Surface patterning with nanoparticles -- 4.7 Nanocapsules -- 4.8 Photonic crystals -- 4.9 Nanoporous materials. | |
| 505 | 8 | |a 5. Miscibility, phase separation, and mechanism of phase separation from the thermodynamic point of view -- 5.1 Thermodynamics of phase separation -- 6. Thermoplastic elastomers: fundamentals and applications -- 6.1 Various properties of TPEs -- 6.2 Applications of thermoplastic elastomers -- 6.3 Recent developments in TPEs -- 6.3.1 Advances in TPEs from living polymerizations -- 6.3.2 Bio-based TPEs -- 6.3.3 TPEs in the biomedical industry -- 6.3.4 TPEs by dynamic vulcanization -- 7. Conclusions and future outlook -- References -- 4 -- Styrenic-based thermoplastic elastomers by anionic polymerization -- 1. Introduction -- 2. General principles for the design of styrenic TPEs -- 2.1 The choice of monomers -- 2.2 The composition of the polymer -- 2.3 Macromolecular architecture -- 3. Linear-type SBCs for TPEs -- 3.1 ABA-type triblock copolymers -- 3.1.1 Polystyrene and polydiene-based TPEs -- 3.1.2 TPEs based on polystyrene derivatives -- 3.1.3 TPEs by postpolymerization reactions -- 3.2 ABC-type triblock terpolymers -- 3.3 Multiblock-type copolymers -- 4. Nonlinear/Complex macromolecular architectures of SBCs for TPEs -- 4.1 Star block copolymers for TPEs -- 4.2 Graft copolymers for TPEs -- 5. Conclusions -- References -- 5 -- New class of thermoplastic elastomers based on acrylic block copolymers -- 1. Introduction -- 2. Synthesis approaches to acrylic TPEs -- 3. Molecular weight between entanglements (Me) -- 4. Approaches to improve the performance of acrylic TPEs -- 4.1 Composition tuning with distinct glass transition mismatch -- 4.2 Complex architectures -- 4.3 Introducing other driving forces -- 4.4 Compounding -- 5. Recent developments and applications in acrylic TPEs -- 6. Conclusions -- Acknowledgment -- References -- 6 -- Polyolefin-based thermoplastic vulcanizates and thermoplastic elastomers: fundamental chemistry problems. | |
| 505 | 8 | |a 1. Polyolefin TPEs and TPVs are not rubbers -- 2. Synthesis -- 2.1 Polyolefin TPEs -- 2.2 Polyolefin TPEs by condensation -- 2.3 Polyolefin TPEs by propagation -- 2.4 Polyolefin TPV -- 3. Synthesis polyolefin-ethylene-octene TPE -- 4. Thermal failure and creep effects -- 5. Plasticizers -- 6. Characterization and morphology -- References -- Further reading -- 7 -- Polypropylene-based thermoplastic elastomers: fundamental blending issues -- 1. Polymer blends -- 2. Thermoplastic elastomers -- 3. Classification of TPEs -- 4. Preparation of PP-based TPEs by blending PP with compatible rubber components -- 5. Preparation of PP-based TPEs by blending PP with compatible rubber components in the presence of compatibilizers -- 6. Preparation of PP-based TPEs by blending PP with incompatible rubber components with physical and reactive compatibilization -- 7. Preparation of PP-based TPE nanocomposites by blending PP with different rubbers (either in the presence or absence of comp ... -- References -- 8 -- Polyolefin-based TPEs: reactive processing -- 1. Introduction -- 2. Dynamic vulcanization through reactive processing -- 3. Cross-linking systems -- 3.1 Sulfur -- 3.2 Peroxides -- 3.3 Phenolic resins -- 4. Morphology and rheological behavior -- 5. Special types of TPEs/TPVs -- 5.1 TPVs based on recycled polymers -- 5.2 TPVs from bio-based thermoplastics -- 5.3 TPVs-based nanocomposites -- 6. Concluding remarks -- References -- Further reading -- 9 -- Thermoplastic elastomers based on polyisobutylene -- 1. Introduction -- 2. PIB-based styrenic TPEs -- 3. PIB-based nonstyrenic TPEs -- 4. PIB-based block copolymer TPE composites -- 5. PIB-containing polyurethane TPEs -- 6. Applications of PIB-based TPEs -- 7. Challenges -- Acknowledgment -- References -- 10 -- Thermoplastic elastomers based on graft copolymers -- List of abbreviations -- 1. Introduction. | |
| 505 | 8 | |a 2. Chemistry of polymer grafting -- 3. Polymer architecture and TPEs -- 4. Graft copolymers-based TPEs -- 4.1 Graft copolymers of polysaccharides -- 4.2 Graft copolymerization of soya bean protein isolated and methyl acrylate -- 4.3 Multigraft copolymer -- 4.4 Polyolefin graft polymer -- 5. Properties and applications of graft copolymers-based TPEs -- 6. Conclusions -- 7. Perspectives -- References -- 11 -- Thermoplastic elastomers (TPEs) from rubber-plastic blends -- 1. Introduction -- 2. Selection of materials for TPE-based blends -- 2.1 Thermoplastics and rubbers -- 3. Preparation of TPEs -- 3.1 Solution casting -- 3.2 Melt blending -- 3.3 Freeze drying -- 4. Fabrication techniques -- 5. Compatibilization -- 5.1 Compatibilization by the action of nanofillers -- 6. Dynamic vulcanization -- 7. Characterization of the TPEs and TPVs -- 7.1 Morphology -- 7.2 Rheology -- 7.3 Mechanical properties -- 7.3.1 Deformation and recovery behavior thermoplastic vulcanizates -- 7.4 Dynamic mechanical analysis -- 7.5 Thermal analysis -- 7.6 Synchrotron X-ray studies -- 7.7 Aging -- 7.8 Diffusion -- 8. Applications of TPEs -- 8.1 Applications of TPVs -- 9. Conclusions -- References -- 12 -- Co-polyesters-based thermoplastic elastomers (Co-PE TPEs) -- 1. Introduction -- 2. Co-polyester developments to thermoplastic elastomers (TPEs) -- 3. Co-polyester thermoplastic elastomers (Co-PE TPEs) -- 3.1 Synthetic route to Co-PE TPEs -- 3.2 Commercial manufacturing of Co-PE TPEs -- 3.3 Properties of Co-PE TPEs -- 3.4 Major applications of Co-PE TPEs -- 4. Published literature on Co-PE TPEs: various soft blocks -- 4.1 Co-PE TPEs with aliphatic ethers: poly(ethylene glycol) (PEGs) and poly(tetrahydrofuran) (p-THF) -- 4.2 Co-PE TPEs with poly(organosiloxane)s -- 4.3 Co-PE TPEs with diacids and diols derived from renewal resource -- 5. Summary and outlook -- Acknowledgment. | |
| 520 | |a This book delves into the advancements in thermoplastic elastomers (TPEs), focusing on their synthesis, properties, and applications. Edited by experts in the field, it covers a wide range of topics including block copolymer phase separation, thermoplastic vulcanizates, and the chemistry of blending and processing TPEs. The book also explores new classes of elastomers based on acrylic and graft copolymers and examines the challenges and opportunities presented by fluorinated and silicone-based TPEs. It addresses both research and commercial development aspects, aiming to provide comprehensive insights into the state-of-the-art technologies and future directions in the field. Intended for researchers, engineers, and professionals in polymer science and materials engineering, this work serves as a valuable resource for understanding the complexities and innovations in thermoplastic elastomer technology. |7 Generated by AI | ||
| 650 | 0 | |a Elastomers. | |
| 650 | 0 | |a Thermoplastics. | |
| 650 | 6 | |a Élastomères. |0 (CaQQLa)201-0021539 | |
| 650 | 6 | |a Thermoplastiques. |0 (CaQQLa)201-0024437 | |
| 650 | 7 | |a elastomer. |2 aat |0 (CStmoGRI)aat300014379 | |
| 650 | 7 | |a thermoplastic. |2 aat |0 (CStmoGRI)aat300014415 | |
| 650 | 7 | |a Elastomers |2 fast |0 (OCoLC)fst00904231 | |
| 650 | 7 | |a Thermoplastics |2 fast |0 (OCoLC)fst01149894 | |
| 700 | 1 | |a Singha, Nikhil K. | |
| 700 | 1 | |a Jana, Sadhan C. | |
| 776 | 0 | 8 | |c Original |z 0323917585 |z 9780323917582 |w (OCoLC)1336986942 |
| 856 | 4 | 0 | |3 ScienceDirect |u https://www.sciencedirect.com/science/book/9780323917582 |