Single atom catalysts design, synthesis, characterization, and applications in energy /
Single Atom Catalysts: Design, Synthesis, Characterization, and Applications in Energy focuses on the synthesis, design, and advanced characterization techniques for single-atom catalyst (SAC) materials and their direct energy conversion and storage applications. This book reviews the emerging appli...
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[2024].
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| 082 | 0 | 4 | |a 541/.395 |2 23/eng/20240215 |1 https://id.oclc.org/worldcat/ddc/E3pCr8FpwcpbTwMHrhFvgQ9rvt |
| 245 | 0 | 0 | |a Single atom catalysts |b design, synthesis, characterization, and applications in energy / |c edited by Prashanth W. Menezes, Debasish Sarkar, Kamlendra Awasthi. |
| 264 | 1 | |a Amsterdam : |b Elsevier, |c [2024]. | |
| 264 | 4 | |c ©2024 | |
| 300 | |a 1 online resource (xi, 256 pages) : |b illustrations (chiefly color) | ||
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| 588 | 0 | |a Description based on print version record. | |
| 505 | 0 | |a Front Cover -- Single Atom Catalysts -- Copyright Page -- Contents -- List of contributors -- 1 Introduction to single-atom catalysts -- 1.1 Introduction -- 1.1.1 Fundamentals of single-atom catalysts -- 1.1.2 Single-atom catalysis: its beginning and evolution -- 1.2 Properties of single-atom catalysts -- 1.2.1 The crucial role of support in influencing intrinsic properties of SACs and the concept of support-metal charge transfer -- 1.2.1.1 Concept of support-metal charge transfer -- 1.2.2 Types of support -- 1.2.2.1 Metal oxides -- 1.2.2.2 Carbon-based materials -- 1.2.2.3 Transition metal chalcogenides (MoS2, MoSe2, WS2, WSe2) -- 1.2.2.4 MXenes -- 1.3 Distinction between single-atom catalysts and grafted organometallic catalysts -- 1.4 Applications of single-atom catalysts -- 1.5 Summary and outlook -- Acknowledgments -- References -- 2 Synthesis techniques for single-atom catalysts -- 2.1 Introduction -- 2.2 Synthetic strategies of single-atom catalysts -- 2.2.1 Wet chemical approaches -- 2.2.1.1 Metal oxide support -- 2.2.1.2 Carbon support -- 2.2.1.3 Metallic support -- 2.2.2 Atomic layer deposition -- 2.2.3 Hydro(solvo)thermal approach -- 2.2.4 Metal-organic frameworks and covalent organic frameworks -- 2.2.5 Solid-state methods -- 2.2.6 Other methods -- 2.3 Conclusion and future outlook -- References -- 3 Characterization techniques for single-atom catalysts -- 3.1 X-ray diffraction and in situ X-ray diffraction -- 3.2 Inductively coupled plasma atomic emission spectroscopy -- 3.3 X-ray photoelectron spectroscopy and in situ X-ray photoelectron spectroscopy -- 3.4 Fourier transform infrared spectrometer and in situ FTIR -- 3.5 Raman and in situ Raman -- 3.6 Transmission electron microscopy and high-angle annular dark-field scanning transmission electron microscopy -- 3.7 Aberration-corrected high-resolution transmission electron microscopy. | |
| 505 | 8 | |a 3.8 Time-of-flight secondary ion mass spectrometry -- 3.9 X-ray absorption spectroscopy -- 3.10 Electron paramagnetic resonance -- 3.11 Electron energy loss spectroscopy -- 3.12 Geometric-phase analysis -- 3.13 First-principles calculations -- 3.13.1 Atomic charge -- 3.13.2 Charge density difference -- 3.13.3 Density of states -- 3.13.4 Projected density of states -- 3.13.5 Density functional theory -- Acknowledgment -- References -- 4 Single-atom catalysts for electrocatalytic oxygen reduction -- 4.1 Introduction -- 4.2 The mechanisms for oxygen reduction reactions -- 4.3 Introduction to SACs catalysts for oxygen reduction reactions -- 4.3.1 Noble metal-based single-atom catalysts for ORR -- 4.3.1.1 Pt-based single-atom catalysts for ORR -- 4.3.1.2 Ru-based single-atom electrocatalysts -- 4.3.1.3 Other precious-metal-based single-atom electrocatalysts -- 4.3.2 Nonprecious metal SACs for ORR -- 4.3.2.1 Fe-based single-atom electrocatalysts -- 4.3.2.2 Co-based single-atom electrocatalysts -- 4.3.2.3 Other nonprecious metal-based single-atom electrocatalysts -- 4.4 Application of SACs for the ORR in electrochemical energy devices -- 4.4.1 SACs catalyst development for fuel cells -- 4.4.2 SACs catalyst development for metal-air batteries -- 4.5 Conclusions and perspectives -- References -- 5 Single-atom catalysts for electrocatalytic oxygen evolution reaction -- 5.1 Introduction -- 5.2 Synthetic strategies of single-atom catalysts -- 5.2.1 Wet chemical strategy -- 5.2.1.1 Coprecipitation method -- 5.2.1.2 Electrochemical deposition method -- 5.2.2 High-temperature pyrolysis -- 5.2.3 Atomic-layer deposition method of deposition of single-atom catalyst -- 5.3 Characterization of single-atom catalysts -- 5.3.1 Scanning tunneling microscopy -- 5.3.2 Aberration-corrected scanning transmission electron microscopy -- 5.3.3 X-ray absorption spectroscopy. | |
| 505 | 8 | |a 5.3.4 Resonant inelastic X-ray scattering -- 5.3.5 Electron energy loss spectroscopy -- 5.3.6 X-ray photoelectron spectroscopy -- 5.3.7 Fourier-transformed infrared spectroscopy -- 5.3.8 M̲ssbauer spectroscopy -- 5.4 Electrocatalytic water splitting -- 5.4.1 Carbon-supported single-atom catalysts -- 5.4.2 Metal compound-supported single-atom catalysts -- 5.5 Mechanism of oxygen evolution reaction with single-atom catalysts -- 5.6 Conclusions -- References -- 6 Single atom catalysts for electrocatalytic hydrogen evolution reaction -- 6.1 Fundamentals of the HER -- 6.1.1 The mechanism of HER -- 6.1.2 Electrochemical characterization parameters for HER -- 6.1.2.1 Overpotential -- 6.1.2.2 Tafel slope and exchange current density -- 6.1.2.3 Electrochemical impedance spectroscopy -- 6.1.2.4 Electrochemical active surface area -- 6.1.2.5 Turnover frequency -- 6.1.2.6 Faradaic efficiency -- 6.1.2.7 Stability -- 6.1.3 Thermodynamic model: Gibbs free energy of hydrogen adsorption -- 6.2 SACs for HER -- 6.2.1 Single metal atoms coordination with N in carbon substrate materials -- 6.2.1.1 M<U+0012>N4 structure -- 6.2.1.2 M-N3 structure -- 6.2.1.3 M-N2 structure -- 6.2.2 Single metal atoms anchored in non-carbon substrate materials -- 6.2.2.1 S-coordinating -- 6.2.2.2 O-coordinating -- 6.2.2.3 P-coordinating -- 6.2.3 Single nonmetallic elements atoms as active centers -- 6.3 Outlook on SACs for HER -- References -- 7 Single-atom catalysts for electrocatalytic carbon dioxide reduction -- 7.1 Introduction -- 7.2 Device assembly and operation parameter -- 7.2.1 Electrolyzer components -- 7.2.2 Working electrode assembly -- 7.2.3 Electrolyte parameters -- 7.2.3.1 Nature of electrolytes -- 7.2.3.2 Effect of pH -- 7.2.3.3 Effect of temperature and pressure -- 7.3 Development of single-atom catalysts for CO2 reduction into value-added products. | |
| 505 | 8 | |a 7.3.1 HER suppression in the SACs -- 7.3.2 SACs for CO2 to CO -- 7.3.2.1 Modulation of the metal atomic center -- 7.3.2.2 Effect of coordination number -- 7.3.2.3 Effect of the coordinated nitrogen type -- 7.3.2.4 Effect of other heteroatoms -- 7.3.2.5 Effect of dual metal atoms -- 7.3.2.6 Effect of surrounding functional groups -- 7.3.3 SACs for CO2 to formic acid/formate -- 7.3.4 SACs for CO2 to CH3OH -- 7.3.5 SACs for CO2 to CH4 -- 7.3.6 SACs for CO2 to C2+ products -- 7.4 Conclusion -- References -- 8 In situ/operando X-ray absorption spectroscopy in small molecule-based electrocatalysis -- 8.1 Introduction -- 8.2 X-ray absorption spectroscopy -- 8.2.1 X-ray absorption near-edge structure -- 8.2.2 Extended X-ray absorption fine structure -- 8.3 In situ X-ray absorption spectroscopy -- 8.3.1 In situ X-ray absorption spectroscopy instruments for electrocatalysis -- 8.3.2 In situ X-ray absorption spectroscopy for nitrogen reduction reaction and CO2RR -- 8.4 Summary -- Acknowledgments -- References -- 9 Catalysts for Li-S batteries -- 9.1 Introduction -- 9.2 Lithium-sulfur batteries -- 9.3 Fabrication of single-atom catalysts -- 9.3.1 Direct pyrolysis method -- 9.3.2 Atomic layer deposition -- 9.3.3 Ball milling technique -- 9.4 Li-S batteries: the mechanism -- 9.5 Challenges of lithium-sulfur batteries -- 9.6 Utilization of single-atom catalysts in other battery application domains -- 9.6.1 Li/Na metal batteries -- 9.6.2 Li/Na-S batteries -- 9.6.3 Li-O2 batteries -- 9.6.4 Zinc-air batteries -- 9.7 Conclusions and outlook -- References -- 10 Conclusions and outlooks -- 10.1 Conclusions -- References -- Index -- Back Cover. | |
| 520 | |a Single Atom Catalysts: Design, Synthesis, Characterization, and Applications in Energy focuses on the synthesis, design, and advanced characterization techniques for single-atom catalyst (SAC) materials and their direct energy conversion and storage applications. This book reviews the emerging applications of SACs in fuel cells, batteries, water splitting, carbon dioxide reduction, and nitrogen fixation. Both noble metal and non-noble metal SACs are discussed, as noble metal-based SACs are highly efficient while non-noble metal-based SACs might have lower associated costs. There is an emphasis on materials' design focused on improving the performance of catalysts based on overall catalytic activity, selectivity, and stability. Specific parameters that impact this performance are emphasized throughout the book, including single-metal atom stabilization, metal-support interactions, and the coordination environment. | ||
| 650 | 0 | |a Catalysis. | |
| 650 | 0 | |a Catalysis |x Industrial applications. | |
| 650 | 0 | |a Nanochemistry. | |
| 650 | 0 | |a Heterogeneous catalysis. | |
| 650 | 0 | |a Metal catalysts. | |
| 650 | 0 | |a Energy conversion. | |
| 650 | 0 | |a Energy storage. | |
| 650 | 6 | |a Catalyse. |0 (CaQQLa)201-0025978 | |
| 650 | 6 | |a Catalyse |0 (CaQQLa)201-0025978 |x Applications industrielles. |0 (CaQQLa)201-0374039 | |
| 650 | 6 | |a Nanochimie. |0 (CaQQLa)000258433 | |
| 650 | 6 | |a Catalyse hétérogène. |0 (CaQQLa)201-0069875 | |
| 650 | 6 | |a Catalyseurs métalliques. |0 (CaQQLa)201-0043160 | |
| 650 | 6 | |a Énergie |x Conversion. |0 (CaQQLa)201-0385643 | |
| 650 | 6 | |a Énergie |x Stockage. |0 (CaQQLa)201-0032707 | |
| 650 | 7 | |a Catalysis |2 fast |0 (OCoLC)fst00848867 | |
| 650 | 7 | |a Energy conversion |2 fast |0 (OCoLC)fst00910026 | |
| 650 | 7 | |a Energy storage |2 fast |0 (OCoLC)fst00910245 | |
| 650 | 7 | |a Heterogeneous catalysis |2 fast |0 (OCoLC)fst00955748 | |
| 650 | 7 | |a Metal catalysts |2 fast |0 (OCoLC)fst01017554 | |
| 650 | 7 | |a Nanochemistry |2 fast |0 (OCoLC)fst01741250 | |
| 700 | 1 | |a Menezes, Prashanth W., |e editor. | |
| 700 | 1 | |a Sarkar, Debasish, |e editor. |1 https://id.oclc.org/worldcat/entity/E39PCjMfM9wV9KhXfWMvwMXt83 | |
| 700 | 1 | |a Awasthi, Kamlendra, |e editor. | |
| 776 | 0 | 8 | |i Print version: |t Single atom catalysts. |d Amsterdam, Netherlands ; Boston, MA : Elsevier, [2024] |z 9780323952378 |w (OCoLC)1373338487 |
| 856 | 4 | 0 | |3 ScienceDirect |u https://www.sciencedirect.com/science/book/9780323952378 |