Processing of Biodegradable Polymers

Biodegradable polymers (BDPs) based on renewable sources have been drawing scientific as well as industrial attention due to their potential to replace fossil derived polymers (FDPs) for a large number of applications. Furthermore, BDPs introduce the viability of bio-degradation at the end of their...

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Главный автор: Kenig, Samuel
Формат: Электронный ресурс eКнига
Язык:неизвестный язык
Опубликовано: Carl Hanser Verlag GmbH and Co. KG 2024
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Online-ссылка:ScienceDirect
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245 1 0 |a Processing of Biodegradable Polymers 
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505 0 |a Intro -- List of Contributors -- Preface -- Contents -- 1 Biodegradable Polymers' Composition, Properties, Processing, and Applications -- Anna Dotan, Amos Ophir, and Samuel Kenig -- 1.1 Introduction to Biodegradable Polymers and Biodegradability -- 1.1.1 Defining Biodegradable Polymers and Biodegradability -- 1.1.2 Fundamental Mechanisms of Degradation -- 1.1.3 Composting -- 1.2 Biodegradable Polymers' Composition, Processing, and Properties -- 1.2.1 Poly(lactic acid) (PLA) -- 1.2.1.1 Composition and Properties -- 1.2.1.2 Biodegradation Mechanisms -- 1.2.1.3 Processability -- 1.2.2 Polybutylene Succinate (PBS) -- 1.2.3 Modified PET -- 1.2.4 Polyhydroxyalkanoate (PHA) -- 1.2.4.1 Composition and Properties -- 1.2.4.2 PHA Stabilization -- 1.2.4.3 Branched PHA -- 1.2.4.4 Properties of PHB -- 1.2.4.5 Biodegradability -- 1.2.4.6 Processability -- 1.2.5 PHBH Polyester -- 1.2.6 Water-Soluble, Biodegradable Polymers -- 1.2.6.1 Starch -- 1.2.6.2 Polyvinyl Alcohol (PVOH) -- 1.2.6.3 Cellulose Ether -- 1.2.6.4 Polyethylene Glycol (PEG) -- 1.2.6.5 Polyacrylamide -- 1.2.6.6 Agarose -- 1.2.6.7 Polyethylene Oxide -- 1.2.6.8 Chitosan -- 1.2.6.9 Sodium Polyacrylate -- 1.3 Biodegradable Polymers -- Summary of Properties -- 1.4 Biodegradable Polymer Blends, Copolymers, and Additives -- 1.4.1 PLA Blends, Copolymers, and Additives -- 1.4.1.1 PLA Additives -- 1.4.1.2 PLA Fillers -- 1.4.1.3 Biodegradable PLA Nanocomposites -- 1.4.2 PHA Blends, Copolymers, and Additives -- 1.4.2.1 PHA Blends -- 1.4.2.2 PHA Additives -- 1.4.3 PTMAT Blends -- 1.5 Conclusions -- 2 Polyhydroxyalkanoates (PHAs): Advancements in Blends, Biocomposites, and Their Commercialization -- Debarshi Nath, Ehsan Pesaranhajiabbas, Akhilesh K. Pal, Bandaru Ramarao, Manjusri Misra, and Amar K. Mohanty -- 2.1 Introduction -- 2.2 PHA-Based Blends. 
505 8 |a 7.1 Introduction -- 7.2 A General Description of Injection Molding -- 7.3 Foam Injection Molding -- 7.3.1 Structural Foam -- 7.3.2 Surface Appearance -- 7.4 Processing of Structural Foams -- 7.4.1 Low-Pressure Process -- 7.4.2 Low-Pressure with Co-Injection -- 7.4.3 Gas Counterpressure -- 7.4.4 High-Pressure Process -- 7.4.5 Mold Opening -- 7.5 Foaming Agents -- 7.5.1 Chemical Blowing Agents -- 7.5.2 Physical Blowing Agents -- 7.5.3 Other Foaming Methods -- 7.6 Machine Requirements -- 7.6.1 Control of Back Pressure -- 7.6.2 Screw Modification -- 7.6.3 Shut-Off Nozzle -- 7.6.4 Special Modification of the Injection System -- 7.7 Process Variables -- 7.8 Foam Injection Molding of PLA -- 7.8.1 Solubility of Physical Blowing Agents in PLA -- 7.8.2 Mold Temperature -- 7.8.3 Injection Flow Rate -- 7.8.4 Back Pressure -- 7.8.5 Foam Injection Molding with Mold Opening: Effect of Opening Rate -- 7.9 Foam Injection Molding of PLA: Additives and Compounds -- 7.9.1 Chemical Modification of PLA -- 7.9.2 Foam Injection Molding of PLA with Talc -- 7.9.3 Foam Injection Molding of PLA with Natural Fibers -- 7.9.4 Foam Injection Molding of PLA-Based Nanocomposites -- 7.9.5 PLA Blends and Compounds -- 7.10 Conclusions and Perspectives -- 8 Microfibrillation as a Facile Processing Technique to Produce Improved Biobased Thermoplastic Blends -- Adel Ramezani Kakroodi, Yasamin Kazemi, and Chul B. Park -- 8.1 Introduction -- 8.2 Microstructure of Microfibrillar Composites -- 8.3 Effects of Microfibrillation on Rheological Properties of Bioplastics -- 8.4 Effects of Microfibrillation on Crystallization Behavior of Bioplastics -- 8.5 Effects of Microfibrillation on Mechanical Properties of Bioplastics -- 8.6 Effects of Microfibrillation on Foaming Ability of Bioplastics -- 8.7 Conclusions -- 9 Electrospinning of Biodegradable Polymers -- Shih-Jung Liu -- 9.1 Introduction. 
505 8 |a 9.2 Variants of the Electrospinning Process -- 9.2.1 Coaxial Electrospinning -- 9.2.2 Other Variants of Electrospinning -- 9.2.3 Needleless Electrospinning -- 9.2.4 Electrospraying -- 9.3 Effects of Processing Parameters on Electrospinning -- 9.4 Biodegradable Polymers for Electrospinning -- 9.4.1 Natural Polymers -- 9.4.1.1 DNA -- 9.4.1.2 Silk Fibroin -- 9.4.1.3 Fibrinogens -- 9.4.1.4 Dextran -- 9.4.1.5 Chitin and Chitosan -- 9.4.1.6 Collagen -- 9.4.1.7 Gelatin -- 9.4.1.8 Hyaluronic Acid -- 9.4.1.9 Cellulose -- 9.4.2 Synthetic Polymers -- 9.4.2.1 Poly(lactic acid) (PLA) -- 9.4.2.2 Poly(lactic-co-glycolic acid) (PLGA) -- 9.4.2.3 Polycaprolactone (PCL) -- 9.5 Summary -- 10 Heat Sealability of Biodegradable Polymers for Packaging Applications and Their Degradation -- Ramin Yousefzadeh Tabasi and Abdellah Ajji -- 10.1 Introduction -- 10.2 Results and Discussion -- 10.3 Conclusions -- Index. 
520 |a Biodegradable polymers (BDPs) based on renewable sources have been drawing scientific as well as industrial attention due to their potential to replace fossil derived polymers (FDPs) for a large number of applications. Furthermore, BDPs introduce the viability of bio-degradation at the end of their life cycle, thus reducing the environmental impact of most FDPs. This book covers the basic properties of BDPs according to their classifications, the rheology of BDPs and their blends, and their numerous applications, with an emphasis on processing: As BDPs possess attractive attributes compared to FDPs (which is discussed in the book), their processing has been investigated using conventional processing technologies. However, BDPs are sensitive to the processing conditions due to their composition, which is tuned to bio-degradation. Hence, special attention has been directed to minimize the in-process degradation and enhance their final processed properties. To remedy some of the BDP processing shortcomings, special additives, fillers, and blends have been incorporated and developed with minimal effect on the BDPs' bio-degradation rate. All of these aspects of BDP processing are considered in this book, including their characteristics in extrusion, injection molding, thermoforming, blow molding, and 3D printing, as well as the processing of recycled BDPs. 
650 0 |a Biodegradable plastics. 
650 0 |a Polymers  |x Biodegration. 
650 0 |a Biopolymers. 
650 6 |a Matières plastiques biodégradables.  |0 (CaQQLa)201-0368419 
650 6 |a Biopolymères.  |0 (CaQQLa)201-0127997 
650 6 |a Architecture.  |0 (CaQQLa)201-0064960 
650 7 |a architecture (discipline)  |2 aat  |0 (CStmoGRI)aat300054156 
650 7 |a Biodegradable plastics  |2 fast  |0 (OCoLC)fst00832000 
650 7 |a Biopolymers  |2 fast  |0 (OCoLC)fst00832670 
856 4 0 |3 ScienceDirect  |u https://www.sciencedirect.com/science/book/9781569908730