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Vegetable oil-based polymers and their surface applications /

Vegetable Oil Based Polymers and Their Surface Applications presents detailed coverage of principles, preparation methods and novel surface uses of vegetable oil based polymers.This comprehensive, state-of-the-art book follows the journey of vegetable oils from seeds to surfaces in a range of advanc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Weitere Verfasser: Sharmin, Eram, Zafar, Fahmina
Format: E-Book
Sprache:Englisch
Veröffentlicht: Amsterdam : Elsevier, 2024.
Schlagworte:
Biopolymers.
Biopolymères.
TECHNOLOGY & ENGINEERING / Materials Science.
TECHNOLOGY & ENGINEERING / Textiles & Polymers.
Biopolymers
Online-Zugang:ScienceDirect
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Inhaltsangabe:
  • Front Cover
  • Vegetable Oil-Based Polymers and Their Surface Applications
  • Vegetable Oil-Based Polymers and Their Surface Applications
  • Copyright
  • Contents
  • Contributors
  • Preface
  • Acknowledgements
  • A
  • Introduction to vegetable oils: chemical reactions and characterization techniques
  • 1
  • Vegetable oils: an introductory chapter
  • 1. Introduction
  • 2. Classification
  • 3. Applications
  • 4. Conclusion
  • References
  • 2
  • Vegetable oils: Biofactories of nature (chemical reactions)
  • 1. Introduction
  • 2. Alkyds
  • 3. Epoxies
  • 4. Polyesteramides
  • 5. Polyetheramides
  • 6. Polyurethanes
  • 7. Conclusion
  • References
  • 3
  • Characterization techniques
  • 1. Introduction
  • 2. Physical and chemical characterization
  • 2.1 Specific gravity (SG)
  • 2.2 Viscosity
  • 2.3 Colour
  • 2.4 Refractive index (RI)
  • 2.5 Epoxide equivalent (EE) (g/eq)
  • 2.6 Acid value (AV)
  • 2.7 Hydroxyl value (HV)
  • 2.8 Iodine value (IV)
  • 2.9 Saponification value (SV)
  • 2.10 Estimation of free isocyanate (-NCO) groups [ASTM D2572-19]
  • 3. Spectral analyses
  • 3.1 Fourier transform infrared (FTIR) spectroscopy
  • 3.2 Nuclear magnetic resonance (NMR) spectroscopy
  • 4. Thermal analyses
  • 4.1 Thermogravimetric analysis (TGA)
  • 4.2 Differential scanning calorimetry (DSC)
  • 5. Morphology
  • 5.1 Scanning electron microscopy (SEM)
  • 5.2 Transmission electron microscopy (TEM)
  • 6. Physico-mechanical analysis and corrosion resistance tests of coatings
  • 6.1 Physico-mechanical tests
  • 6.1.1 Indentation hardness test
  • 6.1.2 Pencil hardness test
  • 6.1.3 Impact resistance test
  • 6.1.4 Bend test
  • 6.1.5 Cross-hatch adhesion test
  • 6.1.6 Gloss test
  • 6.2 Corrosion resistance performance tests
  • 6.2.1 Salt spray test
  • 6.2.2 Humidity test
  • 6.2.3 Corrosion resistance test
  • 6.2.4 Potentiodynamic polarization measurement.
  • 6.2.5 Electrochemical impedance spectroscopy (EIS)
  • 6.2.6 High-performance liquid chromatography (HPLC)
  • 7. Conclusion
  • References
  • B
  • Preparation of vegetable oil-based polymers
  • 4
  • Alkyds from vegetable oils for surface application
  • 1. Vegetable oils
  • 2. Resins for coating industry
  • 3. Alkyd resins
  • 3.1 Synthesis of alkyd resin
  • 3.1.1 Alcoholysis (monoglyceride process)
  • 3.1.2 Acidolysis
  • 3.1.3 FAs process
  • 4. Industrial alkyd production
  • 5. Classification of alkyd resins
  • 5.1 Oil length
  • 5.2 Oxidizing and nonoxidizing alkyds
  • 5.3 Drying and nondrying alkyds
  • 6. Modification of alkyds
  • 6.1 Waterborne alkyds
  • 6.2 Hyperbranched alkyds
  • 6.3 High solids alkyds
  • 6.4 Epoxy esters
  • 6.5 Urethane derivatives
  • 6.6 Alkyds nanocomposites
  • 7. Conclusion
  • References
  • 5
  • Polyesteramides from vegetable seed oils
  • 1. Introduction
  • 2. Diol fatty amide (DFA) from VSO
  • 3. PEAs from DFAs and dicarboxylic acids/anhydrides
  • 4. PEAs from DFAs and polycarboxylic acids
  • 5. Modified PEAs
  • 5.1 Vinylic and acrylic PEAs
  • 5.2 Melamine-modified PEAs
  • 5.3 Urethane-modified PEA
  • 5.4 Metals and metalloids containing PEAs
  • 5.5 PEAs blends and nanocomposites
  • 5.6 Waterborne PEA
  • 6. Conclusion
  • Acknowledgements
  • References
  • 6
  • Vegetable oils-based polyurethanes
  • 1. Introduction
  • 2. Basic components for PUs
  • 2.1 VOs-based diols and polyols
  • 2.1.1 Epoxidation followed by ring opening
  • 2.1.2 Hydroformylation followed by reduction
  • 2.1.3 Transesterification, epoxidation and alcoholysis
  • 2.1.4 Transamidation reaction
  • 2.1.5 Ozonolysis followed by reduction
  • 2.1.6 Thiol-ene coupling reaction
  • 2.1.7 Nucleophilic addition reaction
  • 2.2 VOs-based isocyanates
  • 2.2.1 Reactions for VOs-based isocyanates
  • 2.2.1.1 Curtius rearrangement
  • 2.2.1.2 Hoffman bromide reaction.
  • 2.2.1.3 Metathesis reaction
  • 2.2.1.4 Lossen rearrangement
  • 3. Chemical reactions of VOs-based PUs
  • 3.1 Segmented PUs
  • 3.2 Waterborne PUs dispersion
  • 3.3 Cationic PUs dispersions
  • 3.4 Hydroxy-terminated polyetheramide [PEtA]-based PUs
  • 3.5 Biocompatible PUs
  • 3.6 Reaction of poly (n-butyl acrylate -styrene) (PBS)-based PUs [38]
  • 3.7 PUs from VOs-based isocyanates (nonisocyanate PUs/green PUs) [21]
  • 4. Applications
  • 5. Conclusion
  • References
  • C
  • Applications of vegetable oil-based polymers
  • 7
  • Alkyd resins: Versatile bio-based coating materials
  • 1. Introduction
  • 2. Alkyd resins
  • 3. Modified alkyds
  • 4. Water-soluble alkyd resins
  • 5. Alkyd nanocomposites
  • 6. Alkyd resins from nonconventional resources
  • 7. Conclusion and prospectives
  • Acknowledgements
  • References
  • 8
  • Vegetable oil-based polyesteramide coatings
  • 1. Introduction
  • 2. Poly(ester-amide)s
  • 3. Modified PEA
  • 4. Metal and metalloid-modified PEA
  • 5. Organic moiety modified PEA
  • 6. Waterborne PEA
  • 7. Conclusion
  • Acknowledgements
  • References
  • 9
  • Vegetable oils-based printing inks
  • 1. Introduction
  • 2. Composition of conventional inks
  • 3. Composition of VOs
  • 4. VOs-based inks over petro inks
  • 5. UV curing inks
  • 6. Advantages of VOs-based inks
  • 7. Conclusion
  • Acknowledgments
  • References
  • 10
  • Recent updates on the emerging role of vegetable oils in the development of hydrogel technology for biomedical ...
  • 1. Use of vegetable oils for biomaterials
  • 2. VOs-based hydrogels
  • 3. VOs-based biomedical scaffolds
  • 4. VOs-based hydrogels for wound healing applications
  • 5. VOs-based hydrogels for theranostic applications
  • 6. VOs-based hydrogels as anticancer agents
  • 7. Conclusion
  • Acknowledgement
  • References
  • 11
  • Vegetable oils-based cosmetics
  • 1. Introduction and overview.
  • 2. Traditional uses of VOs in different cultures
  • 3. Properties of VOs in skin care
  • 3.1 Antioxidant properties
  • 3.2 Antibacterial properties
  • 3.3 Emollient properties
  • 3.4 Healing properties
  • 3.5 Hydrating, nourishing and cleansing properties
  • 4. Common VOs used in cosmetics
  • 4.1 Olive oil
  • 4.2 Coconut oil
  • 4.3 Avocado oil
  • 4.4 Jojoba oil
  • 4.5 Oat oil
  • 4.6 Argan oil
  • 4.7 Soybean oil
  • 4.8 Chyuri butter/oil
  • 4.9 Sea buckthorn oil
  • 4.10 Flaxseed oil
  • 5. Advantages and business prospects of VOs
  • 5.1 Advantages of VOs in cosmetics industries
  • 5.2 Cosmeceutical business prospects of VOs
  • 6. Conclusion
  • Acknowledgments
  • References
  • 12
  • Vegetable oils-based lubricants
  • 1. Introduction
  • 2. VO used for lubricants, their advantages and applications
  • 2.1 Sunflower oil
  • 2.2 Jatropha oil
  • 2.3 Castor oil
  • 2.4 Palm oil
  • 2.5 Karanja oil
  • 3. Conclusion
  • Acknowledgements
  • References
  • 13
  • Vegetable oils in nanoparticles synthesis
  • 1. Introduction and overview
  • 2. VOs-mediated NPs synthesis methods
  • 3. NPs synthesized using VOs and their applications
  • 3.1 Lipid nanoparticles
  • 3.2 Metal nanoparticles
  • 3.2.1 Silver nanoparticles
  • 3.2.2 Gold nanoparticles
  • 3.3 Metal oxide nanoparticles
  • 3.3.1 Iron oxide and related nanoparticles
  • 3.3.2 Zinc oxide and related nanoparticles
  • 3.3.3 Copper oxide nanoparticles
  • 3.4 Polymeric nanoparticles using VOs
  • 3.4.1 Polyurethane nanoparticles
  • 3.4.2 Chitosan nanoparticles using VOs
  • 3.5 Other nanoparticles
  • 3.5.1 Nanocarbons
  • 3.5.2 Cadmium sulphide and other nanoparticles
  • 4. Benefits of VOs in nanoparticles synthesis
  • 5. Factors affecting the synthesis of nanoparticles using VOs
  • 6. Concluding remarks
  • Acknowledgements
  • References
  • 14
  • Green synthesis of metal nanoparticles using essential oils and plant extracts.
  • 1. Introduction
  • 2. Classification of green synthesis routes for NPs
  • 3. Biological synthesis of NPs
  • 3.1 Green synthesis of metal NPs using EO
  • 3.2 Steps to consider before planning the synthesis of NPs
  • 3.3 Applications of green NPs
  • 4. Future perspectives
  • References
  • 15
  • Vegetable oil-based polymer nanocomposites for surface applications
  • 1. Introduction
  • 2. Nanocomposites and bionanocomposites
  • 3. VO-based bionanocomposites
  • 3.1 Surface applications of VO-based polymer nanocomposites
  • 3.1.1 Alkyd nanocomposites
  • 3.1.2 Polyesteramide nanocomposites
  • 3.1.3 Polyetheramide nanocomposites
  • 3.1.4 Polyurethanes and their nanocomposites
  • 3.1.5 Polyamides and their nanocomposites
  • 3.1.6 Epoxies and their nanocomposites
  • 4. Surface applications of VO based polymer nanocomposites
  • 4.1 Coatings
  • 4.2 Antibacterial behaviour
  • 4.3 Wound dressings
  • 4.4 Tissue engineering
  • 5. Conclusion
  • Acknowledgements
  • References
  • 16
  • Essential oils and plant extracts-based corrosion inhibitors for metal surfaces
  • 1. Introduction
  • 2. Essential oils-based corrosion inhibitors for metal surfaces
  • 3. Plant extracts (pretreatment and extraction)
  • 4. Plant material for extraction
  • 4.1 Leaf as plant material
  • 4.2 Fruit as plant material
  • 5. Plant extracts as corrosion inhibitors
  • 5.1 Experimental approach
  • 5.2 Simulation approach
  • 6. Proposed corrosion protection mechanism adopted by plant extracts and essential oils
  • 7. Conclusion
  • Acknowledgements
  • References
  • 17
  • Antimicrobial importance of essential oils
  • 1. Essential oils
  • 1.1 Definition
  • 1.2 Physical properties
  • 1.3 Chemical composition
  • 1.4 Methods of preparation
  • 1.5 Pharmaceutical importance of EO
  • 1.6 Examples of some EOs with their antimicrobial activity
  • 1.6.1 Basil EO
  • 1.6.2 Peppermint EO
  • 1.6.3 Rosemary EO.

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